I am currently a level 16 ench and have done a fair amount of solo charm killing. They say it starts to get easier in the 30s, but if you take your time you can do it at 12. The best advice I can give is that you want to always keep what your killing rooted. This way when your charm drops you only need to worry about 1 mob.
Beyond that you can experiment with nuking your target to try and kill a few mobs with 1 pet or try and get your pet and target to around 15-20%, invis to break charm and nuke both for full xp.
Sow helps a lot and so does cha gear.
Edit... Also, it's a good idea to charm blue mobs as even and higher mobs seem to break more often.
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