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Old 11-25-2013, 01:40 AM
DrKvothe DrKvothe is offline
Sarnak


Join Date: Aug 2013
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Originally Posted by kylok [You must be logged in to view images. Log in or Register.]
@ DrKvothe after doing some light reading on the subject on Homochirality I found some information that was pretty consistent with what my ochem teacher was telling me - "The emergence of chirality consensus as a natural autoamplification process has been associated with the 2nd law of thermodynamics." He's got a PhD in physical chemistry and a main portion of his research dealt with converting the equation for mixing entropy from intensive to extensive. He has done this successfully btw - so get ready for some books to get big fat addendums added to 'em.
assuming a selfreplicator must be homochiral (or nearly) the spontaneous formation of such a molecule from a racemic monomer pool is exponentially less likely than from a homochiral pool. The chance of a polymer length n being homochiral from a racemic pool is 1 in .5^n. The generation of a homochiral pool of monomers makes molecular selfreplicators much more likely to arise, but few reasonable scenarios have been published to date. If we knew what molecules actually made up the first molecular selfreplicator, we could probably figure it out...
 


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