This is a few days old so maybe not helpful now but if you don't even know a spell lineup to use, then it's probably best to start out charming some pretty easy stuff in outdoor zones to build up the muscle memory of what to do when you get a break.
I don't know a spell lineup for druids. But a lot handling charm breaks is to get all of the steps you need to do to get your pet re-charmed on autopilot so you don't even have to think about it.
The ring is really convenient but not required. You can always sell it if you need pp. I'd definitely get one.
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