Either one will be a lot of fun solo. The Necro will be pretty powerful and efficient from level 12 or so. The Shaman doesn't really come into its own until 24 at least (mine dinged 24 this morning, and the addition of regen/canni is very welcome and makes soloing quite a bit faster).
The Shaman is more gear-dependent (though still not to the degree of a Monk or Warrior, for example) so your twink dollars will make more of a difference there.
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