ENC mez is fixed duration based on the level of the spell, if it lands, it lands.
CHA will make your mez land more consistently (this is the main reason to raise CHA for enchanters imo)
Charm is random duration and if CHA affects it it is hard to tell, CHA does allow charm to land more consistently.
lull/pacify etc checks against your CHA when determining whether you pull agro if the spells are resisted. I don't think it affects whether the spells succeed or fail.
With high CHA and a blue mob, it is rare for Charm and Mez to be resisted unless the mob has particularly high MR (Especially charm)
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