Not to necro an old thread but in case any other new Enchanters read this: Don't do your first foray charm killing in dungeons. Do it in an outdoor zone, preferably an area with few wanderers (even better a static camp where you can single pull if you don't want to deal with breaking a couple mobs). Get the hang of it, get used to knowing what to do when Charm breaks so that you don't freak out. Once you get that down you can try doing it in dungeons.
Also, always have your Rune buff up.
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