Why anyone would want to do this is truly beyond me. May as well make it a hardcore character for maximum frustration.
But with infinite patience yes. Rogues can farm poisons and use them to fear kite/proc slow even before they can farm a snare weapon. Combine with solo backstabs. You can farm a Dragoon Dirk in NRO in your mid/late teens and that will last you for a long time. In your 40s you can sneak around Droga and try to find a Canyoneer Pike.
I have thought about doing a rogue twink and seeing how much I could squeeze out of poisons. Consensus is some are pretty OP but that farming the ingredients/plat costs / storage of materials just doesn't make it efficient for leveling. But since you're doing SSF and efficiency isn't the point, sounds perfect.
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