Welcome. Tbh you probably want to roll a good solo alt for when your bro isn't around, so Necro, Druid, Shaman, Mage or Enchanter. All have their strengths and drawbacks. It is possible to solo as a cleric, but not optimal. What classes do you have for your duo with your bro?
Can't really advise on groups very much as I'm pretty much a solo only player, but afaik the main grouping places at low levels are East Commonlands, Oasis, Crushbone, Unrest. Do a /who all Dial and ask nicely for someone from <Dial a Port> if they can port you from Toxx to Butcherblock or West Commonlands (remember to tip if you can afford) and then ask someone in /ooc to bind you in a city.
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