In PvP it's because the proc is an unresistable spinstun which just means death to the target when an assist train hits them. In PvE, it's because it is the only bow in the game with 200 range and a detrimental proc. The way archery works, the arrows you shoot take time to travel to the target so they will not hit instantly, but if you proc on the shot then the proc hits the target instantly. This combination of maximum range and a proc means that a Windstriker can obtain FTE on a raid target instantly from 350 range (using 150 range arrows) when it procs. Nothing else comes close to that.
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