It really depends on gear. Often warriors are tanking with proc weapons that aren't the best of the best ratios. The SK can tank normal stuff with any weapon. Normal duo combos the warrior will be higher you're in it for the long haul either way.
At some point, grinding at least, it's less about dps and more about capacity to kill. Being able to pull, snare, and fear (if needed) along with a shaman is a great combo. As a warrior your kill targets will be more specific since the sham will have to CC the extra targets. Monks are great with shams but a sk can work as well.
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