I'd recommend Shaman+SK or Shaman+Monk. Any combination of races that appeal to you and her.
In addition to the already-mentioned positives in terms of duoing and raiding, you'll also have the benefit of easy-to-find 6man groups since youll have a Priest+Tank.
Also add a Chanter to make an immensely powerful trio that could hold just about any camp with ease.
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