CH far more efficient than getting another pet and having to rebuff it while duo'ing. AoE mezz saves a spellbar slot, and most enchanters toward level 60 have a sufficient mana pool to support the mana cost. I can honestly say I don't ever recall NOT resisting the aoe mezz on myself.
As far as what to do if you're sitting at full mana, do whatever you need to to increase efficiency. With rogue charmed pets, I'll dip into melee range behind the slowed mob with bedlam and rune on, so that the mob turns around. Color flux, then color skew. Pet gets a couple backstabs off, etc. Rebuffing at full mana if you're sitting there is a good idea. Doesn't hurt to throw a nuke at it every now and then if you're actually full mana and nothing else to do in a duo.
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