Not sure what you mean about enchanters not being fun in parties. Enchanters kick butt in parties. Charm DPS is unmatched by any class. Plus CC duty is pretty fun if you've got a puller that doesn't insist on single-pulling everything.
But as far as twinking, they definitely won't benefit from gear as much as other classes. Since they have no heals at all, you're going to rely on rune to keep your HP from dropping. If you ever get low hp, there's not much you can do besides sit and wait. The last thing you want is to have a bad charm break when you're already at low health.
If you want to twink an enchanter, I would recommend a Zlandi heart with a maple leaf mask for treeform illusion (+5 regen), and then keep troll illusion up.
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