When you are chaining charm kills together the easier way imo is to just get used to not killing both mobs each fight. Let your pet and the non-charmed mob fight...kill one of them, doesn't matter which. Then either pull another mob and sick your low health pet on it or charm a fresh mob and send it against the low hp mob...and repeat. Occasionally you'll get the scenario of both being low hp at the same time and you can just wipe them both and rest or start over.
This will also let you do the "meat grinder" style charm killing. Where you sick your pet on five or six mobs...root them all and then proceed to break your charm and kill your pet when it gets low life. repeat now with one of the five mobs you rooted on top of each other.
If you insist on keeping it to only two mobs and wiping them both each pull you can do that but you'll end up with fractional hp left on one (you can try the root trick to keep a fleeing mob fighting) frequently.
As you get more confident you'll find that it is actually easier and much more efficient to kill 5 or 6 social mobs with root/charm then it is to 1 on 1 them.
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