The pre-level 12 DOT set (Poison bolt, clinging darkness, disease cloud) will typically not pull agro from your pet as long as you let pet get mob down to 80% or so.
If you sit you are more likely to be attacked, so if you plan to sit (after dots) make sure you let pet do a little more damage.
At level 12 you get strong DOTS and I think you should let pet get mob to 50 or 60% to avoid agro (just test with trial and error).
At level 16 you get Feign Death which means you can go nuts on dots and just periodically FD to wipe agro (unless FD mechanics are different than on live/what I remember).
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