Barbarian Shaman is fine for solo. Any class can be soloed to 50, some are just faster than others, some have steeper learning curves, some are more gear dependent, but at this stage in the timeline there's plenty of cheap gear that is better than what was available in Classic to get to 50.
50+ solo is a trickier thing no matter what you play and there isn't one class that can solo every soloable camp, so it comes more to what you have more fun playing solo.
Barbarian Shaman is one of the easier ones. 500pp or less in gear/spells can get you to 50 and that's easy enough to farm up before 20.
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