Unfortunately to figure out which is better would take a significant amount of testing that i'm really not willing to do at the moment.
My gut feeling is that Duelist would be better overall though. On the off chance you pop duelist and get a lot of Backstab misses obviously Deadeye would have been better but in my experience you're normally going to hit over 50% of your backstabs which would make Duelist the better option.
If you really want to test it though I'd suggest making a spreadsheet that tracks avg hit/miss, anything near 50% might support using Deadeye, but I feel like it's going to be more like 65% hit chance.
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