How beginner we talking? Necro and Enchanter and Mage are great soloers and do well as a duo in any combination though Necro/Enc and Mage/Enc are better than any other combo just for the benefit of mana regen.
Shaman/Monk is great.
Enchanter/Cleric is a great combo as well once the cleric hits 39 it becomes inhuman. The great thing about Enchanter/Cleric combo is the amazing group versatility. You are the core of a group, throw up a LF3M Tank and DPS PST and you will have a wicked group built in no time flat. You can easily duo anything and you already have CC + Heals covered for starting a group (these are the hardest things to find if you don't have friends online).
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