I would say probably the "best" duo is with Paladin, especially up to level 50. Paladin can pull, tank, heal, CC, and snap agro with Flash of Light while the Rogue goes stab stab stab. Paladin also has unparalleled caster mitigation, which is key for this duo. I have duoed Mistmoore, Sol B, LGuk and other zones completely effectively with Rogue. It was great XP and tons of fun, also very easy to pick up a Shaman or Chanter (or really anybody else) then you're really good to go. Pal, Rog, Wiz is also a ton of fun.
Wizard Rogue is also an excellent duo, you just have to do it mostly in outdoor zones (or indoor zones with big areas to run) Wizard can spam flux staff, stun, and snare and kite away while the Rogue stabs.
I have done both methods extensively and they are both great. I suggest indoor zones due to better XP, which is a general EQ rule of thumb. The big thing is take whatever you can get and move your XP bar however you can.
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