Warlords Rage is my personal theoretical favorite. It's a massive str buff ( like 70) with some AC, but it deals 70 dd and 600 DoT in 30 seconds. I used that in the rogue BoTB first round and very nearly killed a person who played a rogue on red.
As far as practical poisons go, the root poison has a 50% slow in it. If you really wanted to solo, that would be the ideal one to go with.
The problem is the expense (6-10k pp to get 250 with high dex gear) and massive inventory crowding that poison making entails. It's really not a viable thing to use in PvE. Your role in a group is to deal a lot of damage, not to have utility. You deal a lot of damage for free, and no one would notice your awesome utility. They WOULD you sitting down for 10 seconds (apply poison timer) while they are fighting the mob and think you're an awful rogue, however.
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