Pick Pocket wasn't on a separate loot table on Live. Pick Pocket has been fixed on P99 and now works very classically as far as I can tell. You can pick pocket humanoid mobs, steal one type of coin or item at a time, and can't take the very last coin of each type that a mob has.
More information.
__________________
Live:
Nubben, Level 80 Rogue, formerly of <Silens Dauthus> now of <Dark Bane> (Mithaniel Marr)
P99:
Nubben, Level 16 Rogue