This is a hard question to answer. If I understand you right and you just want to use soloing as an effective means to level, then I would say necro(1-60) or enchanter (20-60) are the best. Shaman is a very poor class from 1-24... then a semi-poor class until 34 when things pick up a bit, but it is a class to consider for the end-game benefits. In fact, I think Shaman has the easiest road from 45-60 solo, if and only if you can afford JBB and can get epic around lvl 54-56.
If you are talking about being an effective soloer at 60, then either Shaman or Enchanter. Shaman probably edges out enchanter @ 60 considering velious is impending.
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