I'm partial to the Shaman / SK combo. Monk is good, but can't tank mobs in the second half of the game (50+). High levels, the shaman can basically root rot mobs while the SK tears through them 1 at a time.
In terms of gear availability to a new player, I'd probably go shaman/enchanter. Lots of melee twinks running around and I think a well played caster duo can mostly bypass the twink limitations.
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