Great info from Mazeri and Adament...
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I'd recommend reading the Enchanter guides on the Project 1999 Wiki
for more info. They are PACKED with great tips.
A few more quick tips.
1) Keep target mob rooted at all times and slowed too for more safety.
2) Have CHA buff on you at all times.
3) Tash mob you want to charm first and charm will last longer.
4) Use Color Flux/Shift to stun mob when charm breaks, to give
you some time to recast Charm.
5) Break Charm/Kill pet first, then kill target to ensure full XP for both kills.
6) When duoing with a healer, keep pet around with heals and put haste
on it. Best and easiest XP I have found.
7) Charm blue or light blues only...anything higher will break charm quickly.
Good luck!
Selenia